The objective of this dissertation is two-fold: (i) to assess the management of metrological function of an oil and gas exploration and production unit within a large energy enterprise in Brazil; and (ii) to propose recommendations for its improvement. Since the creation of Portaria Conjunta n 1 ANP/Inmetro, in June 2000, oil and gas exploration and production activities in Brazil have suffered an accelerated process of organizational reengineering and adapted all their measurement installations to attend the new regulatory framework. In this context, the motivation of this research arose from Petrobras’needs to have an assessment tool capable of measuring efficiency and efficacy of its metrological function, incorporating in the analytical framework elements concerning organizational culture and development of competences towards attendance of new metrological requirements. The methodology comprises: (i) bibliographic and documentary research on the central themes of dissertation; (ii) propose of a conceptual model for assess metrological function management, which links theoretical approaches reviewed; (iii) development and application of a survey questionnaire, based on this conceptual framework; (iv) case study focusing on the metrological function at Exploration and Production Operational Unit of Espírito Santo and its four subunities; (v) formulation of improvement actions for Petrobras metrological function at the selected unities, and suggestions for future research and replication in other organizational contexts. As a conclusion, it can be said that the proposed assessment model fulfilled expectations and assumptions formulated at the very beginning of this research. According to the opinion of managers and teams involved, the model is an useful management and learning tool for improve the management of metrological function and has a large potential for replication in other organizational contexts from the empirical evidences achieved.