Título: | QUENCHING AND PARTITIONING OF NI-ADDED HIGH STRENGTH STEELS: KINETICS MODELLING MICROSTRUCTURE AND MECHANICAL PROPERTIES | ||||||||||||||||||||||||||||||||||||||||
Autor: |
ANA ROSA FONSECA DE AGUIAR MARTINS |
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Colaborador(es): |
FERNANDO COSME RIZZO ASSUNCAO - Orientador |
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Catalogação: | 03/DEZ/2007 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||||||||||||||||||||||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=10952&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=10952&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.10952 | ||||||||||||||||||||||||||||||||||||||||
Resumo: | |||||||||||||||||||||||||||||||||||||||||
High strength steels containing significant fractions of
retained austenite have been developed in recent years and
are the subject of growing commercial interest when
associated with the TRIP phenomenon during deformation. A
new process concept, Quenching and Partitioning, has been
recently proposed for production of steel microstructures
containing carbon-enriched austenite. The heat treatment
sequence involves quenching to a temperature between the
martensite-start (Ms) and martensite-finish (Mf)
temperatures, followed by a partitioning treatment, above
or at the initial quench temperature, designed to enrich
the remaining untransformed austenite with the carbon
escaping from the supersaturated martensite phase, thereby
stabilizing the retained austenite phase during the
subsequent quench to room temperature. To enable the
austenite enrichment, competing reactions, principally
carbide precipitation, must be suppressed by appropriate
alloying elements, such as Si and/or Al. The concept
assumes a stationary martensite/austenite interface and the
absence of shortrange movements of iron and substitutionals
elements. The condition under which partitioning occur has
been called Constrained Carbon Equilibrium (ECC), due to
the restriction in movement of the interface and the
assumption that only carbon equilibrates its chemical
potencial at the interface. In this work, a group of four
alloys was investigated, containing different additions of
C and Ni and containing Si, Mn, Mo e Cr. These alloys were
designed to preclude bainite formation at the partitioning
temperatures of interest. Several heat-treatments, were
performed in these alloys, using the Q&P concept, to
evaluate its effect on the resulting microstructure and
mechanical properties. Each alloy was quenched at selected
temperatures and partitioned from 350 to 450°C for times
ranging from 10 to 1000s. Microstructural characterization
was performed by optical microcoscopy, scanning and
transmission electron microscopy, while X-ray diffraction
was used to determine both the fraction and the carbon
content of the retained austenite. Partitioning kinetics
were simulated with DICTRATM. The results were analyzed
taking into consideration the scale of the microstructure,
as well as the partitioning temperature. Tensile test
results indicated that very high levels of strength with
moderate toughness can be achieved confirming the potential
of the Q&P to produce a superior combination of mechanical
properties.
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