Título: | SYNTHESIS, PROCESSING AND CHARACTERIZATION OF CU-CNT NANOCOMPOSITE MATERIALS | ||||||||||||||||||||||||||||||||||||||||||||
Autor: |
MARTIN EMILIO MENDOZA OLIVEROS |
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Colaborador(es): |
IVAN GUILLERMO SOLORZANO NARANJO - Orientador EDUARDO DE ALBUQUERQUE BROCCHI - Coorientador |
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Catalogação: | 01/ABR/2009 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||||||||||||||||||||||||||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=13223&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=13223&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.13223 | ||||||||||||||||||||||||||||||||||||||||||||
Resumo: | |||||||||||||||||||||||||||||||||||||||||||||
The increasing interest in nanostructure materials in
recent years has provided
incentive to develop nanostructure composite materials with
metal matrix, reinforced with
carbon nanotubes. In the present work, copper matrix nano
composite with carbon
nanotubos (2% wt) was produced by chemical synthesis
method. The procedure
begins by the copper nitrate dissociation containing SWCNT
and anionic tensoactive
agent at 250°C, followed by in-situ reduction at 350°C,
under hydrogen atmosphere at
pressure of 1atm. CuO and Cu formation was confirmed by X
ray diffraction at
the moment of dissociation and reduction respectively. CNTs
presence was
detected at both steps by this characterization method.
Transmission Electron
Microscopy analysis, estimate particles grain size of 30nm
for CuO powder while
Cu powder particles were observed to be in the 100-300nm
range, showing good
dispersion of CNT. Bulk nano-composite pellets of the
reduced material were
obtained by pre-compactation under uniaxial pressure of 17
MPa followed by
issostatic pressure of 150MPa. Sinterizing of the compacted
material was carry
out at 650°C under Argon atmosphere by 15 min. Scanning
Electron Microscopy
and Transmission Electron Microscopy analysis of the
sinterized material showed an heterogeneous grain size
distribution in the 100nm to 4 ìm range. Electric
resistivity measures show that the nanocomposite material
has lower resistivity at
low temperature (2x10(-6) ? .cm) at 83°K than the copper
without carbon nanotubes
(5.9x10(-6) ? .cm).
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