The present work embodies two studies: a global analysis of cogeneration systems and an absorption refrigeration cycle model. The first study presents the main equations for energy and exergy balances of a cogeneration system operating with two distinct prime movers (a gas turbine and an internal combustion engine, both powered by diesel oil). For cooling production, an absorption chiller, driven by the prime movers` waste heat, and an auxiliary vapor compression chiller are employed. The energy and exergy balance equations were applied to each component of the system, composing a non-linear system of algebraic equations whose solution provides the performance of the system under different operating conditions. The second study is part of a broader project aiming at the development of an absorption refrigeration system. A mathematical model is presented, describing a small-size absorption refrigeration installation employing a water-ammonia mixture as working fluid. Mass and energy conservation equations were applied to each component of the cycle. Thermodynamic properties of the working fluids were calculated at each point of the cycle. Also, simplifying assumptions were applied. The resulting model was applied to simulate the behavior of an existing system. Comparison of predicted results with experimental data was satisfactory. A parametric analysis was also carried out with the simulation model. The models of both studies were implemented in ESSA software. Simulations were carried out so as to analyze the systems under particular operational conditions and to assess the influence of the main variables on system performance.