Título: | ASSESSMENT OF THE MOBILITY OF ELEMENTAL CONTAMINANTS AND ENVIRONMENTAL IMPACTS DUE TO THE INAPPROPRIATE DISPOSAL OF FLUORESCENT LAMPS | ||||||||||||
Autor: |
LAIS NASCIMENTO VIANA |
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Colaborador(es): |
TATIANA DILLENBURG SAINT PIERRE - Orientador |
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Catalogação: | 07/AGO/2023 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=63554&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=63554&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.63554 | ||||||||||||
Resumo: | |||||||||||||
Although fluorescent lamps (FL) are being replaced by LED (light emitting
diode), most FL are disposed of improperly and recycling rates are still generally
low (4 percent in China, 5 percent in Brazil, 7 percent in Canada, less than 10 percent in Japan). Because of their
composition, FL can have a significant environmental impact. Thus, in the present
study, we used different analytical techniques with the objective of characterizing
the raw phosphor material of FL, quantifying the elements mobilized by synthetic
landfill leachate and acid rain solutions, and evaluating the environmental impacts
related to the disposal of lamps through life cycle analysis (LCA) for the city of Rio
de Janeiro scenario. The analysis of the raw material by fluorescence and X-ray
diffraction (FRX and DRX) points to a complex composition of solid phases, with
a predominance of Ca, P and Al, presence of rare earth elements, As and others.
Through microwave-assisted near-total acid extraction, concentrations varying
from 1 to 165 g kg-1 were found for Al, Ba, Ce, Eu, La, Mn, P, Sr, and Y in the raw
material, and more than 700 mg kg-1
of Hg. Leaching with synthetic solutions was
performed with and without agitation, with 0.6 g of sample, 1 mL of solutions, and
3 h of exposure. The test produced the mobilization of several elements with
concentrations reaching 23.5 more or less 0.4 mg kg-1
(Hg) in acid rain, and 34.0 more or less 1.0 mg
kg-1
(Sr) in landfill leachate. Due to the danger of some elements, the amounts
extracted, although low, are worrying, and consecutive leaching, common in a real
disposal scenario, can aggravate the situation. The life cycle analysis indicated that
the lamps generate greater environmental impacts in the categories of terrestrial
ecotoxicity, non-carcinogenic human toxicity, global warming potential and
depletion of fossil resources. The analysis indicated that increasing recycling rates
can reduce most impacts to the environment by 70 to 90 percent.
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