ETDs @PUC-Rio
| Título: | STUDY OF COPPER(II) AND ZINC(II) COMPLEXES WITH SOME POLYAMINES AND PHOSPHOCREATINE OR ATP | |||||||
| Autor: |
NATALIE WAISSMANN SZYFMAN |
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| Colaborador(es): |
JUDITH FELCMAN - Orientador |
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| Catalogação: | 13/SET/2011 | Língua(s): | PORTUGUESE - BRAZIL |
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| Tipo: | TEXT | Subtipo: | THESIS | |||||
| Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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| Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=18244&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=18244&idi=2 |
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| DOI: | https://doi.org/10.17771/PUCRio.acad.18244 | |||||||
| Resumo: | ||||||||
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Some binary systems of Cu(II) and Zn(II) with polyamines (PA=En, Tn, Put, Spd and Spm), and ternary complexes (MLPA) of Cu(II) and Zn(II), where L is PCr or ATP, and PA is one of the five polyamines, were studied. The study was performed in aqueous solution using potentiometry, ultraviolet-visible, Raman, NMR and EPR spectroscopies, and, calculations of the lowest stabilization energy for formed complexes and molecular modeling. The stability constants were determined by potentiometry. The order of the values of stability constants of the systems with Cu(II) is: CuPut |
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