This research is a result from analyze of work`s processes that are constituted in the diversity among productive units of solidarity economy in Brazilian contemporaneousness. In this purpose the study searches to clear up the potentiality of these practices in the constitution of a new sociability from the emphasis on extraeconomic aspects. Through semi-structured interviews based on experiences from people that are in ten productive units of solidarity economy in the state of Espírito Santo.Bibliographic research, documents about the movement, participation on events, on plenary assemblies of Forum Estadual de Economia Popular Solidária/FEPS, and our participation on first and second stages to elaborate the map of solidarity economy in the state of Espírito Santo supported our investigation. The discovery of potentiality of educational processes in solidarity economy demands a constant critical efforts, setting these kind of actions in the context of dynamic of social relations that faced with new kinds of employments with a tendency to incorporate to the capital . However the analyze notices that these experiences work also such as a space that reveals different forms of popular culture, like a set of loose practices and representations. Thus, it is an analyze that concerns the potentialities of the movement of solidarity economy in Brazil, in the 1990s, inserted in a society of classes, it becomes in a complex and contradictory social historic movement.