Título: | DEVELOPMENT AND CHARACTERIZATION OF HIGH-DENSITY POLYETHYLENE COMPOSITES REINFORCED WITH SOAPSTONE WASTE | ||||||||||||
Autor: |
GIULIA SIMAO BARRETO DE SOUSA |
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Colaborador(es): |
JOSE ROBERTO MORAES D ALMEIDA - Orientador |
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Catalogação: | 18/NOV/2021 | Língua(s): | ENGLISH - UNITED STATES |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=56010&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=56010&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.56010 | ||||||||||||
Resumo: | |||||||||||||
A novel sustainable material was developed using a mineral waste as
filler for polymeric composites. Soapstone is a mineral typically found in
abundance in communities that rely heavily on artisanal crafts as a source
of income and which are often in a situation of social vulnerability. Rock
recovery in those activities is low and the waste disposal is done with little
control, which can be hazardous to the environment and the health of
the local residents. Thus, to use this residue to reinforce the properties
of a polymer with a wide range of applications, such as polyethylene, can
lead to positive economical, social and environmental returns. A thorough
characterization of the residue was done with automated image analysis, Xray
diffraction, infrared, and Raman spectroscopy. The waste particles were
incorporated into a high-density polyethylene (HDPE) matrix in three compositions:
10, 20 and 30 wt percent. X-ray microtomography was used to quantify
the filler volume fraction, void content, and the microstructural homogeneity
of the composites. It was found that the soapstone particles have a
strong tendency of forming clusters in the HDPE matrix, however, statistical
analysis revealed that the volumetric filler distribution was homogeneous
throughout the samples. Rheological, tensile and creep tests assessed the influence
of the particles on the polymer s processing conditions and practical
mechanical behavior. A relevant increase in viscosity and shear stress was
observed at lower shear rates for higher filler loadings. The addition of soapstone
waste particles successfully decreased creep strain and increased both
yield strength and elastic modulus of HDPE. However, the incorporation
of higher amounts of filler altered the fracture mechanism and considerably
decreased ductility and creep rupture time of the polymer. The relationship
between the microstructure and the macroscopic mechanical behavior was
investigated by fitting tensile test data with macro-mechanical models from
the literature, which allowed the quantification of the interfacial bonding.
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