The development and/or adaptation of numerical methods when applied to power systems stability computer simulations in time domain are of interest due to the difficulties related to the solution of the algebraic differential equations (ADEs) which represent the network and its components. The solution of networks operating under heavy load conditions and extremely compensated is difficult due to the ill-conditioning of the Jacobian matrix, numerical instability and singularity. It can happen, for instance, when solving linear problems of type Ax = b. In order to overcome this and other difficulties, this thesis aims to contribute in the numerical aspect of the problem applying the Generalized Minimal Residual method – GMRES to solve the problem. The idea is to work over the preconditioner quality constructed based on the Jacobian matrix. It is shown that, if this matrix is well conditioned, the quality of the resulting preconditioner is good enough to the GMRES reaches convergence in few iterations. It is seen through numerical experiments using different test-systems and different operating conditions as well, that the Jacobian matrix conditioning is improved if scaled, normalized and reordered before the preconditioner construction, resulting, in fact, in a high quality preconditioner, improving the GMRES performance.