Supply chains (CS) are pressured to implement initiatives to make their performance more sustainable. For example, the challenges imposed by the energy transition for the oil and gas sector and its SC stand out. Guide SC towards sustainability requires a coordinated, integrated, and collaborative effort between multiple partners. A crucial factor in evolving the sustainability trajectory of SC is the learning that takes place during the implementation of collaborative sustainability initiatives. However, there is not enough evidence in the literature about how and at what levels the learning process occurs, as well as about its characteristics and form of interaction between partners. The objective of the thesis is to deepen the understanding of the characteristics of the learning dynamics and their influence on the sustainability trajectory in the SC. The thesis uses the methods of systematic literature review and multiple case studies. As the main results, it presents a typology and integrated theoretical framework on SC sustainability learning and proposes a process-based approach for empirical investigation of the phenomenon. The research was conducted in three large international multinationals and in their SC operating in Brazil. The results show that SC s sustainability trajectory is cumulative, recurrent, and non-linear, resulting from successive learning opportunities emerging from collaborative sustainability initiatives at SC. Adopting abductive reasoning, the thesis provides a first step in the elaboration of a theory of learning about SC sustainability and coined the concept of SC plasticity.