Título: | RHEOLOGICAL AND THERMAL PROPERTIES OF MULTIFUNCTIONAL HEXAGONAL BORON NITRIDE DISPERSIONS BASED IN XANTHAN GUM FOR USE IN WATER-BASED DRILLING FLUIDS | ||||||||||||
Autor: |
YAGO CHAMOUN FERREIRA SOARES |
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Colaborador(es): |
MONICA FEIJO NACCACHE - Orientador RICARDO JORGE ESPANHOL ANDRADE - Coorientador |
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Catalogação: | 16/DEZ/2024 | Língua(s): | ENGLISH - UNITED STATES |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=68816&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=68816&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.68816 | ||||||||||||
Resumo: | |||||||||||||
In recent decades, the demand for oil and gas has surged, prompting the
identification of new oil fields in challenging reservoir environments those
characterized by high-pressure and high-temperature (HPHT) conditions. The
development of high-performance aqueous-based drilling fluids with tailored
properties aims to enhance extraction processes in the oil industry and reducing
environmental contamination mainly caused by oil-based fluids. This study aims to
investigate how variations in parameters such as temperature, pressure and
concentration impact the thermal and rheological properties of xanthan gum
suspensions with oxidized hexagonal boron nitride (hBN-oxi) nanostructures. The
thermal conductivity was significantly increased by the addition of hBN-oxi
nanoparticles (6.0 wt percent suspension) to the base fluid, reaching an increase of up to
12 percent at 70 degrees C. These nanostructures played a crucial role in preserving the thermal
conductivity of xanthan gum suspensions even at elevated temperatures. The
presence of nanoparticles at the highest concentration induced a yield stress in the
fluid and when subjected to high shear rates, experienced a viscosity drop of only
16 percent at 80 degrees C. These adverse effects of temperature and pressure on viscosity were
mitigated by the interaction between the polymer matrix and hBN-oxi. Overall, the
study highlighted the potential of boron nitride as a nanoadditive for conventional
drilling fluids, showing that properly designed formulations can improve
performance even in challenging conditions without causing harm to the
environment, thanks to the material s high thermal and chemical stability.
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