Título: | MICROSCALE FLOWS OF THIXOTROPIC LIQUIDS | ||||||||||||
Autor: |
CARLOS EDUARDO SANCHEZ PEREZ |
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Colaborador(es): |
MARCIO DA SILVEIRA CARVALHO - Orientador DANMER PAULINO MAZA QUINONES - Coorientador |
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Catalogação: | 10/JUL/2023 | Língua(s): | ENGLISH - UNITED STATES |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=63138&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=63138&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.63138 | ||||||||||||
Resumo: | |||||||||||||
Many particle suspensions behave as thixotropic-viscous materials
and they are present in different industrial processes, including coating
applications. Specifically, the production of battery electrodes involves slot
coating of a thixotropic liquid. In most cases, the flow of slurries and other
particle suspensions is described by using a time-independent model that
assumes the viscosity to be solely a function of the local deformation rate.
However, the viscosity of thixotropic fluids is associated to the evolution
of its microstructuring level, which does not change instantaneously with
the shear stress (or deformation rate). In the case of imposing constant
shear stress (or shear rate), the microstructure evolves until reaching an
equilibrium state; but this process takes time. Even in a steady-state flow,
the liquid flows through regions where there are significant changes in the
levels of shear stress and the flow is transient in a Lagrangian point of
view. Therefore, assuming that the viscosity at each point of the flow is the
steady-state viscosity described by a time-independent model may lead to
an inaccurate flow description. The relative magnitude of the characteristic
response time of the liquid and the residence time of the flow becomes an
important parameter. This is particularly relevant in small scale flows with
very small residence time. Flows of a thixotropic-viscous liquid through
a constricted microcapillary and in a slot coating process were analyzed
here using two rheological models: a time-independent model (TIM) and
a thixotropic model that takes into account the liquid time-dependent
response. The resulting set of fully coupled, non-linear equations was solved
by the Galerkin and SUPG Finite Element Method. The results show that
the use of a TIM to describe thixotropic viscous materials, such as some
particle suspensions, can lead to very large errors on the predicted flow
behavior. Furthermore, time-independent models are not able to predict
complex flow phenomena, like hysteresis, which could lead to unstable flows.
These inaccuracies highlight the need for a more complete model that takes
into account time-dependency of the flowing liquid in a certain range of flow
parameters.
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