Título: | ANTICORROSIVE ORGANIC COATING NANOFILLED WITH REDUCED GRAPHENE OXIDE IN CO2 ENVIRONMENT | ||||||||||||
Autor: |
ANANIAS ALEXANDRE EMMERICK |
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Colaborador(es): |
IVANI DE SOUZA BOTT - Orientador |
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Catalogação: | 14/JUN/2023 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=62857&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=62857&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.62857 | ||||||||||||
Resumo: | |||||||||||||
This research evaluated the corrosion resistance of an epoxy resin-based coat,
reinforced with 0.1 and 0.5 wt% of reduced graphene oxide (rGO), applied to AISI
1020 carbon steel. Immersion tests in aqueous solution with 3.0 wt% NaCl
saturated with CO2, in a pressurized cell at 70 bar at 40⁰C, for 528 h. The coating
was evaluated by Pull-Off Test, microhardness (Shore D hardness), and Scanning
Electron Microscopy (SEM). The quality of the coating anchoring to the
substrate, porosity, and thickness was evaluated. The presence of pits on the
surface of the metallic substrate was assessed by Optical Microscopy (OM). The
results obtained indicated that the addition of rGO contributed to greater corrosion
resistance and provided better structural integrity to the coating. The results
obtained showed that the coatings under the three conditions, as received and 0.1
and 0.5wt% rGO additions had the same efficiency in protecting the metallic
substrate, avoiding pitting. Pore refinement occurred for 0.1wt % rGO, and the
addition of 0.5wt% promoted a drastic reduction in pore density. The addition of
rGO did not influence on the Shore D Hardness of the coatings. For a precorrosion
test, the coating with 0.1wt% of rGO obtained higher pore density and
lower hardness value, followed by 0 wt% and later 0.5 wt% of rGO. For the post
corrosion test, the order is reversed. The results of the post corrosion test indicated
that the porosity allowed the permeation of the solution in the coatings and is
related to the bubbles and blistering, which influenced the hardness. The addition
of 0.1 and 0.5 wt% or rGO did not affect the coating anchoring, obtaining
reasonable accommodation in the irregularities of the substrate metallic surface.
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