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Título: CHEMICAL AND MECHANICAL CHARACTERIZATION OF THE DEPOSITION FILM FORMED DURING THE CORROSIVE PROCESS OF AISI 1080 IN A CONFINED ENVIRONMENT CONTAINING CO2
Autor: ANA CAROLINA ARAUJO ANDRADE
Colaborador(es): FERNANDO COSME RIZZO ASSUNCAO - Orientador
JAVIER ALEJANDRO CARRENO VELASCO - Coorientador
Catalogação: 30/MAI/2023 Língua(s): PORTUGUESE - BRAZIL
Tipo: TEXT Subtipo: THESIS
Notas: [pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio.
[en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio.
Referência(s): [pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=62734&idi=1
[en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=62734&idi=2
DOI: https://doi.org/10.17771/PUCRio.acad.62734
Resumo:
During oil exploration and production, operational difficulties need to be overcome in CO2 injection to increase production. In the presence of water, CO2 reacts and forms H2CO3, which can corrode the carbon steel present in flexible pipes. Several factors influence the corrosive process, including the partial pressure of CO2, the temperature, pH of the medium and the volume of solution/exposed metallic area (V/A) ratio. Thus, the objective of this work was to evaluate the composition and mechanical properties of the corrosion products deposited on the surface of carbon steel 1080 immersed in synthetic sea water, at a temperature of 40 C degrees, for 15 and 121 days. To evaluate the influence of the partial pressure of CO2, the tests were carried out at 1, 10 and 20 bar of CO2, and to evaluate the influence of the V/A ratio, the tests were carried out at 1 mL.cm-2 and 20 mL. cm-2 . Corrosion rates were determined using the gravimetric method, characterizations of corrosion products were performed by Optical Microscopy (OM), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and X-Ray Scattering (XRD). Additionally, Nanoindentation was used to determine the mechanical properties of the formed film. From the OM, the formation of two films was identified in almost all conditions studied. When evaluating the influence of pressure, no significant variations in the corrosion rate were observed. As for the results obtained to evaluate the effect of the V/A ratio, it was possible to conclude that the confined environment significantly reduces the corrosion rate. When evaluating the mechanical properties of the films, it was possible to observe that in all cases, the hardness and the elastic modulus are lower in the inner film when compared to the outer film. This may be related to the formation of a more compact outer layer, consisting predominantly of small FeCO3 grains, according to the results obtained through SEM and XRD.
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