Título: | EVALUATION OF THE CREEP BEHAVIOR OF ABS WITH FLAME RETARDANTS ADDITIVES | ||||||||||||
Autor: |
THIAGO MOREIRA DA SILVA |
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Colaborador(es): |
JOSE ROBERTO MORAES D ALMEIDA - Orientador DANIEL CARLOS TAISSUM CARDOSO - Coorientador |
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Catalogação: | 02/MAI/2023 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=62438&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=62438&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.62438 | ||||||||||||
Resumo: | |||||||||||||
Acrylonitrile-Butadiene-Styrene (ABS) is a polymer of great industrial
use, being used in numerous products. Many of its applications require a high
resistance to combustion, either due to the presence of electrical charges (Joule
Effect) or exposure to high temperature environments. However, ABS, like
most polymers, is not as resistant to combustion, requiring the use of Flame
Retardant (RC) additives. The introduction of these additives can, however,
lead to changes in the mechanical properties, so it is necessary to compare the
behavior of the material with and without additives. Particularly important is
long-term behavior such as fluency. Thus, in this work, the creep behavior of
ABS without additive and of three ABS/RC systems was evaluated. A system
employing a commercial bromine-based additive (ABS − Br) was used, which
served as a basis for comparison and two recently developed systems employing
bio-retardants, namely: tannic acid (TA) and ammonium polyphosphate (APP)
. The test results showed that the commercial additive did not cause a change
in creep life compared to ABS without additive. On the other hand, the
results indicated that the creep life was reduced when the APP additive was
incorporated and that it increased when the TA was added. Experimental
data from creep tests were used to evaluate the viscoelastic behavior of the
four groups of materials. ABS had its behavior adequately represented by the
Burgers model, as well as ABS with bromine-based additive. The model that
best described the behavior of ABS with APP was the modified Burgers model
(Streched Burgers). Not all ABS samples with TA showed fluence in the time
interval used and the model that best described the behavior was the standard
linear solid.
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