Título: | REMOVAL OF MANGANESE FROM WATERS AND INDUSTRIAL EFFLUENTS WITH USE OF HYDROGEN PEROXIDE | ||||||||||||||||||||||||||||||||||||||||
Autor: |
JULIANA SANTOS DOS SANTOS |
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Colaborador(es): |
LUIZ ALBERTO CESAR TEIXEIRA - Orientador |
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Catalogação: | 07/ABR/2005 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||||||||||||||||||||||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=6237&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=6237&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.6237 | ||||||||||||||||||||||||||||||||||||||||
Resumo: | |||||||||||||||||||||||||||||||||||||||||
I order to remove metals from
waters and aqueous effluents generally are employed
traditional methods which
involve neutralization, hydrolysis and precipitation of
hydroxides using a base.
Manganese must be removed from waters and aqueous effluents
down to a
concentration limited by Brazilian law which is of 0.1 mg/L
for waters and 1.0
mg/L for aqueous effluents. The work carried out herein
investigated the removal
of manganese (II) using the following oxidants: oxygen,
hydrogen peroxide, and
Fenton reagent, with the aim to identify a process that
could be more efficient than
the simpler hydroxide precipitation. Results are discussed
of experiments made
with synthetic solutions of 1000 mg/L manganese (II) with
the objective of
developing a route that could favour the removal of that
metal to the levels
established by Brazilian environmental law (resolution
CONAMA 20 / 1986).The
experiments were conducted in pH 7 to 10, at temperature
ambient and 80 oC,
with reaction times of 5, 15 and 30 minutes. Hydrogen
peroxide was used in
excess levels of 100 and 200% for the reaction:
Mn2+ (aq) + H2O2 (aq) -> MnO2 (s) + 2 H+ (aq)
Amongst the conducted experiments, both hydrogen peroxide
and the Fenton
reagent were shown to be most effective, allowing final
concentrations of
manganese less than 0.3 mg/L, at ambient temperature, in pH
values lower than
those required for precipitation without oxidation or with
O2 (air).
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