Título: | RADIOLYSIS AND SPUTTERING FTIR ANALYSIS OF NITROGENOUS BASES IRRADIATED BY (KE)V ELECTRONS UNDER ASTROPHYSICAL CONDITIONS | ||||||||||||
Autor: |
VINICIUS PESSANHA REGO |
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Colaborador(es): |
ENIO FROTA DA SILVEIRA - Orientador CINTIA APARECIDA PIRES DA COSTA - Coorientador |
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Catalogação: | 21/JUN/2022 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=59652&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=59652&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.59652 | ||||||||||||
Resumo: | |||||||||||||
The origin of life is still an open question in science. Among the possible
answers, panspermia is a widely discussed alternative. To investigate this
possibility, the development of models that describe the behavior of molecules
interacting with cosmic rays is extremely important. For this purpose, thin films of
different thicknesses of nitrogenous bases - adenine, cytosine, guanine, and
thymine - were deposited on ZnSe disks to be irradiated by 1.0 and 0.50 keV
electrons. Adenine was irradiated under different temperatures. After each partial
irradiation, optical spectroscopy in the infrared region (FTIR) was used to monitor
changes in spectral characteristics. It is observed that the destruction cross sections
of irradiated nitrogenous bases are approximately 10 raised to -16 square cm and, for adenine, this value increases at low temperatures. In comparition to glycine data, the estimated half-life of pure
adenine when processed at 1 au by the solar wind is about 100 days. The cross
section varies very little when the film thicknesses are increased from 10 to 30 nm,
and the bases follow the order: cytosine, adenine, guanine and thymine,
respectively, from the least to the most radioresistant. To better analyze the
experimental data, they are compared with predictions obtained with the CASINOextended algorithm. They are in good agreement if radiolysis and sputtering are
considered.
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