The popularity of platforms for the storage and transmission of video content has created a substantial volume of video data. Given a set of actors present in a video, generating metadata with the temporal determination of the interval in which each actor is present, and their spatial 2D localization in each frame in these intervals can facilitate video retrieval and recommendation. In this work, we investigate Video Face Clustering for this spatio-temporal localization of actors in videos. We first describe our method for Video Face Clustering in which we take advantage of face detection, embeddings, and clustering methods to group similar faces of actors in different frames and provide the spatio-temporal localization of them. Then, we explore, propose, and investigate innovative applications of this spatio-temporal localization in three different tasks: (i) Video Face Recognition, (ii) Educational Video Recommendation and (iii) Subtitles Positioning in 360-video. For (i), we propose a cluster-matching-based method that is easily scalable and achieved a recall of 99.435 percent and precision of 99.131 percent in a small video set. For (ii), we propose an unsupervised method based on them presence of lecturers in different videos that does not require any additional information from the videos and achieved a mAP approximately 99 percent. For (iii), we propose a dynamic placement of subtitles based on the automatic localization of actors in 360-video.