Título: | STUDY OF THE BIO-CHARCOAL APPLICATION, OBTAINED FROM SUGARCANE BAGASSE, ON THE FREE ALUMINUM RETENTION: A CONTRIBUTION REGARDING ITS USING IN THE SOILS CONDITIONING | ||||||||||||
Autor: |
JORDAN GIOVANNY NARVAEZ PANTOJA |
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Colaborador(es): |
EDUARDO DE ALBUQUERQUE BROCCHI - Orientador |
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Catalogação: | 20/JUN/2017 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=30307&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=30307&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.30307 | ||||||||||||
Resumo: | |||||||||||||
The Immobilization of contaminants using functionalized charcoal (CVf), or also called biochar (BC) in water and soil treatment gets an increasingly important role and it is considered as a good alternative of remediation. In addition, currently it has taken account the CVf production, using biomass, or agricultural by-products. The biochar has a High cation exchange capacity (CEC), large surface area as well as a big micropores size. These factor will generate a significant adsorption of contaminating metals. Thus, the CVf plays an important role in the control of contaminants. The objective of this work is to evaluate samples of functionalized Biochar (CVf) which was obtained from the sugarcane bagasse in order to determine the aluminum retention for its possible applicability in contaminated soil. The project was divided into stages. Firstly, it was developed a protocol in order to obtain functionalized charcoal (CVf). In the second part, aluminium adsorption test were carried out in CVf, varying the pH, amount of sorbent and metal concentration. Finally, it was determined the optimum conditions for the maximum metal removal on liquid media, being pH 5, time of 4 hr, and CVf concentration of 10 mg/l, following its possible application in the soil conditioning. It was necessary to carry out chemical and complementary analysis of the samples such as SEM-EDS, infrared (FTIR), and atomic absorption spectrophotometry to characterize the product. The behavior of the adsorption phenomenon was demonstrated by testing the Langmuir and Freundlich models. The results of the characterization and adsorption process were similar to those reported in the literature, and the adsorption data were coupled to the Freunlinch model. As expected, in the interaction of the material obtained and the soil, the CEC and pH, increases with the increase of CVf concentration as well as the amount of aluminum retained, concluding that functionalized charcoal (CVf) is a good option for soil conditioner, especially in acid soils for free aluminum removal.
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