Título: | DEVELOPING OF A STRIP TEST FOR FE(+2) IN DOCUMENTS WRITTEN WITH IRON-GALL INK | ||||||||||||||||||||||||||||||||||||
Autor: |
ALEXANDRE VILELA OLIVEIRA DE SOUZA |
||||||||||||||||||||||||||||||||||||
Colaborador(es): |
JOSE MARCUS DE OLIVEIRA GODOY - Orientador |
||||||||||||||||||||||||||||||||||||
Catalogação: | 22/OUT/2009 | Língua(s): | PORTUGUESE - BRAZIL |
||||||||||||||||||||||||||||||||||
Tipo: | TEXT | Subtipo: | THESIS | ||||||||||||||||||||||||||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
||||||||||||||||||||||||||||||||||||
Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=14461&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=14461&idi=2 |
||||||||||||||||||||||||||||||||||||
DOI: | https://doi.org/10.17771/PUCRio.acad.14461 | ||||||||||||||||||||||||||||||||||||
Resumo: | |||||||||||||||||||||||||||||||||||||
During about 600 years, official documents and orders were written with
real iron gall ink. Only by the end of the Nineteenth Century and beginning of the
twentieth century it was gradually replaced by synthetic dyes. Thus, the presence
of such documents with ink in archives and libraries is significant. However, the
reaction system formed between the components used in the manufacture (ferrous
sulfate and tannic acid) and cellulose, known as the Fenton system, can lead to
destruction of the document. In this case, the Fe (+2) ion has a role of paramount
importance. In this context, a reliable and non-destructive measurement of the
presence of this ion in the documents, by tests of touch, becomes a powerful tool.
There is a tape, available in the market, indicator for the detection of iron in the
original, using an insoluble indicator, the bathofenanthroline. However, even this
can cause red stains in the original. This study presents the development of a new
identifier strip test of Fe (+2), with a lower possibility of the appearance of red
spots in the original. For this, we tested the parameters that influence the reaction
medium of the tape, such as distribution of the superficial indicator reagent, type
of paper, change in the reaction medium and adding a protective layer. It has been
carried out a study of possible interfering reaction in iron-batofenantrolina. The
comparison between the tape currently in the market and the one developed in this
study was done using the digital processing of the resulting color of the reaction
of Fe (+2) ions and indicator batofenantrolina. This allows us to evaluate the best
performance of the tape carried in patterns used for testing.
|
|||||||||||||||||||||||||||||||||||||
|