Título: | PRODUCTION AND CHARACTERIZATION OF HYDROGENATED AMORPHOUS CARBON THIN FILMS DEPOSITED IN METHANE PLASMAS DILUTED BY NOBLE GASES | ||||||||||||||||||||||||||||||||||||||||||||
Autor: |
GIL CAPOTE RODRIGUEZ |
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Colaborador(es): |
FERNANDO LAZARO FREIRE JUNIOR - Orientador |
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Catalogação: | 13/NOV/2003 | Língua(s): | PORTUGUESE - BRAZIL |
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Tipo: | TEXT | Subtipo: | THESIS | ||||||||||||||||||||||||||||||||||||||||||
Notas: |
[pt] Todos os dados constantes dos documentos são de inteira responsabilidade de seus autores. Os dados utilizados nas descrições dos documentos estão em conformidade com os sistemas da administração da PUC-Rio. [en] All data contained in the documents are the sole responsibility of the authors. The data used in the descriptions of the documents are in conformity with the systems of the administration of PUC-Rio. |
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Referência(s): |
[pt] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=4120&idi=1 [en] https://www.maxwell.vrac.puc-rio.br/projetosEspeciais/ETDs/consultas/conteudo.php?strSecao=resultado&nrSeq=4120&idi=2 |
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DOI: | https://doi.org/10.17771/PUCRio.acad.4120 | ||||||||||||||||||||||||||||||||||||||||||||
Resumo: | |||||||||||||||||||||||||||||||||||||||||||||
In this work, the effects of the dilution of the precursor
methane atmosphere by three noble gases (Ar, Ne and He) on
the mechanical properties and the microstructure of
hydrogenated amorphous carbon films (a-C:H) are presented.
The influence of the precursor atmosphere (for Vb=-350 V)
and the variation of the self-bias voltage (Vb) are
studied. The influence of the substrate temperature also is
studied for three temperatures 250 K, 300 K and 420 K for
films deposited in atmospheres of 100% CH4 and 2% CH4 + 98%
Ar. The films were deposited by Plasma Enhance Chemical
Vapor Deposition (PECVD). The mechanical and structural
properties were investigated with the use of the nuclear
techniques (Rutherford backscattering and elastic recoil
detection analysis), infrared and Raman spectroscopies,
atomic force microscopy, contact angle measurements,
internal stress and hardness measurements. The results
shown that the precursor atmosphere dilution by noble gases
did not induce substantial modifications in the
microstructure or in the mechanical properties of the
films. On the other side, the results shown that the
composition, the microstructure and the mechanical
properties of the films are strongly dependent on the ion
bombardment regime. The dependence of the mechanical and
structural properties of the films as a function of the
substrate temperature was also investigated. Experimental
results had been obtained from the film roughness
measurements using atomic force microscopy. These results
suggest the transition from predominantly
adsorption/diffusion mechanisms to the predominance of the
ballistic processes in the formation mechanisms of the a-
C:H films.
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