Over the last years, a strong trade-off between crude oil offer and oil product demand has been posed in Brazil: while the oil produced in Brazil is getting heavier, its` products must be light, constrained by rigid specifications. Hence, the country needs to adapt its refineries and logistic network to this new profile. In this context, a long term analysis of the integrated oil chain is a relevant task. This analysis helps the decision maker to choose projects that should be considered in portfolio investment. During the decision process, it is important to take into account uncertainties related to some parameters: crude oil prices, crude oil offer, product prices, expected demand and others. By doing that, it is possible for the analyst to evaluate a project portfolio considering risks. The present work proposes a methodology for optimization under uncertainty, applied to the study of a portfolio investment for the downstream oil industry, employing both stochastic programming and portfolio optimization techniques. The study is focused on a linear programming model that maximizes the expected net present value (NPV) along the specified time horizon and risk level. Two approaches have been proposed to measure risk: Conditional Value-at-Risk (CVaR) and Minimax. The results show that the investment choice in the oil chain varies with the imposed risk level.