The current entrepreneurial context, made up of ever quicker changes and challenges, leads companies to adapt their activities to the requirements imposed by the market. The most difficult, and at the same time the main point of learning, is not to limit the organizational changes to a strictly instrumental view of people at work. Learning, besides propitiating the necessary adaptations to the daily life, also propitiates a transforming change in the organizations, extending their creativity and innovative capacity. In the areas of Pedagogy, Psychology and Cognitive Biology, the interpersonal relationships are considered important participants in the learning process. The studies on companies from the Communion Economy project show that the way the interpersonal and interorganizational relationships are led make up one of their distinctive competitive features. In this research, the quality of the interpersonal relationships in an Communion Economy enterprise organization are studied, attempting to understand how they might ease or hamper the processes of organizational learning. Its conclusion confirms that the quality of the interpersonal relationships favors the learning of tasks and behaviors in the company which was the subject of the study.