In this present work, the Mode Matching technique is applied in the analysis and project of coaxial structures. The feed junction is one of the critical points of the project of discone antennas when broadband performance is expected. Usually, these junctions are composed of nonuniform sections of coaxial waveguide and, to guarantee the necessary mechanical rigidity of the structure, some sections are filled with dielectric material. The project of these feed junctions requires a compromise between frequency band, compact structure, minimal losses, and mechanical rigidity. Due to the discontinuities, numerical methods are used to predict the electromagnetic behavior. Here, Mode Matching technique associated with an optimization algorithm is employed in the adjustment of the dimensions of the coaxial waveguide sections, seeking the minimization of the return loss and the enlargement of the antenna bandwidth. Several types of junctions are explored and their performance is compared.