This work presents a supervised Non-Intrusive Appliance Load Monitoring (NILM) method, or energy disaggregation, for residential consumption, which aims to decompose the aggregate energy consumption data collected from a single measurement point into device-level consumption estimation using steady state analysis techniques with no need to install individual meters on appliances. The proposed methodology considers two steps to face the problem. Firstly, periodical appliances are modeled from the estimation of Fourier series parameters and extracted from the total power measured. Secondly, the results obtained are combined with a Mixed Integer Linear Programming proposed to disaggregate the remaining appliances, which minimize the difference between the total aggregated load and the sum of the estimated load curves per appliance. A study case is performed with a real case to validate the proposed method and indicates that the model can be useful for practical applications, such as helping evaluate the possibility of the consumers changing the modality of their tariff contract from the conventional tariff to the new Brazilian modality called white tariff.