In Brazil, during the 1990s, there was a predominance of vertical companies in the electricity sector, belonging to the state and federal governments, which in the course of the restructuring and privatization process suffered a deverticalization of their activities into generation, transmission, distribution, and commercialization. After the beginning of this privatization process, the National Electric Energy Agency (ANEEL) was created, which is responsible for regulating the activities of the Brazilian electricity sector. These changes have led to different market models characterized by the strong use of the transmission systems. In this scenario, it was defined by ANEEL that the distribution concessionaires must pay the transmission companies for the use of their equipment. Thus, it is necessary to inform the Transmission System Usage Amount (MUST) for each connection point and tariff period by means of the Transmission System Use Agreement (CUST). In case of exceeding a specified percentage of the contracted amounts, the contractor will have to pay penalties. This dissertation aims to present a new methodology to determine the optimal value of MUST, based on flexible static equivalents, probabilistic power flow, and stochastic optimization techniques, in order to balance the energy transport and penalty costs. First, a flexible and accurate network reduction technique is used. Second, the uncertainties arising from the load, generation, and topology of the network are mapped at the connection points under analysis. Third, a simple stochastic optimization technique is used to obtain the MUST to be contracted by the electric power distributor at each border bus. Finally, the proposed methodology is used in the IEEE RTS academic system in order to demonstrate its efficiency, and the obtained results are widely discussed.