This work aims to investigate the influence of high temperatures on the flexural behavior of pultruded glass fiber reinforced polymeric profiles made by the pultrusion process. Four different composites constituted by isophthalic polyester, ester vinilic or phenolic resins reinforced with E-glass fibers arranged in form of rovings, continuous filaments and veils are analyzed. Theories associated with the mechanical and physical behavior of glass fiber reinforced polymer composites are presented and the results of an experimental program involving bending tests, before and after exposure to temperatures up to 320 degrees Celsius, thermogravimetric material degradation analyzes and tensile tests, are reported and analyzed. The analysis of the mechanical properties involved: study of modulus of elasticity, tensile strength and strain. The results showed that, despite the apparent degradation, the mechanical properties showed improvements at temperatures close to 200 degrees Celsius and did not show significant changes after exposures up to 320 degrees Celsius. The composites of the vinyl ester matrix showed the highest strengths and the phenolic matrix composite showed lower resistant and fragile behavior. Finally, samples of the materials were analyzed in the scanning electron microscopy (SEM), before and after exposure to high temperatures, in order to verify microstructural damages in its structure.