The present work is concerned with the modeling of the coupling between mechanical and termal phenomena. The thermomechanical coupling is important in some problems like those involving inelastic cyclic deformation in metallic structures. A systematic procedure to obtain thermodynamically admissible constitutive equations is presented. Such procedure has a strong thermodynamic basis and is used to obtain a constant theory to model the anisothermal behavior of metals and alloys. Two kinds of thermomechanical couplings can be identified: the internal coupling, related with the internal dissipation in the mechanical process and the thermal coupling, related with the dependence of the material parameters in the constitutive equations on temperature. The theory is particularized to elasto-viscoplastic materials. Uniaxial simulations were performed to study the heating of metals due to complex mechanical loadings and the behavior of metals subjected to high temperature gradients. A damage variable is introduced in the model to study the influence of the thermomechanical coupling in processes involving the degradation of the material like in low-cycle fatigue.